Place oven rack 4 inches from broiler; preheat broiler to high. Preheat rimmed baking pan in oven 10 minutes. In large bowl, whisk vinegar and marinade mix. Brush steak with ½ the vinegar mixture.
Remove pan from oven; spray with cooking spray. Place steak on prepared pan; broil 8 minutes. In medium bowl, toss peppers and pineapple with remaining vinegar mixture.
Turn steak; add pepper mixture to pan around steak. Broil 7 minutes or until internal temperature of steak reaches 145° for medium-rare (or to desired doneness). Transfer steak to cutting board; let stand 5 minutes. Slice steak against the grain; serve with pepper mixture.
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* The % Daily Value (DV) tells you how much a nutrient in a serving of food contributes to a daily diet. 2,000 calories a day is used for general nutrition advice.